Overall Mini PCI-e is a fairly unloved interface, but we’ve seen the reverse of this hack before, a Mini PCI-e to USB adapter used to add a 12-axis sensor to a laptop.
This showed that the Raspberry Pi would happily talk with a VL805-based USB 3.0 PCIe expansion card, as well as a Realtek RTL8111-based Ethernet card, but not a number of other PCIe cards.